Abstract

We have developed a new concept for the formation of geochemical types of salt lakes which explains the nature of their different chemical composition under close landscape-climatic and geological-geochemical conditions. The extensive field hydrogeochemical material and thermodynamic calculations demonstrate that in addition to evaporation, the interaction with rocks plays a great role in the formation of the composition of lakes. This interaction begins in the catchment area of a particular lake and continues directly in the lake. Such processes are most widespread in soda lakes, which is confirmed by the presence of the highest pH values (9.0-10.7). Besides, one of the most important processes is sulfate reduction, which results in hydrogen sulphide in lakes fundamentally changes the geochemical environment from oxidizing to reducing one and leads to a change in the oxidation state of many elements, changing their migration ability and, therefore, the ability for concentration or binding by secondary minerals. The presence of an oxidizing environment and sulphides in rocks gives additional sources for sulfates, which ensures the formation of sulfate-type lakes.

Highlights

  • Chemists studied the chemistry of salt lakes and associated salts and they explained their high salinity mainly by evaporation of sea water

  • In Russia, and later in the USSR scientists examined the salts of the present-day lakes of the Crimea Peninsula, the Volga region, the Caspian area, and Siberia, which were more accessible for study [2]

  • It is typical for any region of the world – Africa, Australia, China, Mongolia, the Crimea Peninsula, the Western Siberia, and the Baikal region [8, 9, 10, 11, etc.] The same diversity of lakes is typical for the Transbaikalia region[12,13, 14]

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Summary

Introduction

Chemists studied the chemistry of salt lakes and associated salts and they explained their high salinity mainly by evaporation of sea water. Great contribution to the development of modelling methods was made by French scientists who studied many salt lakes in France [6, 7 etc.] It is typical for any region of the world – Africa, Australia, China, Mongolia, the Crimea Peninsula, the Western Siberia, and the Baikal region [8, 9, 10, 11, etc.] The same diversity of lakes is typical for the Transbaikalia region[12,13, 14].

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