Abstract
Development of amino acid-based natural deep eutectic solvents (DESs) pretreatment technology on lignocellulosic biomass is a promising approach to biorefinery. In this study, for arginine-based DESs with different molar ratios, the viscosity and Kamlet-Taft solvation parameters were quantified to evaluate the pretreatment performance on bamboo biomass. Further, microwave assisted DES pretreatment was eminent, evidenced by 84.8% lignin removal and increased saccharification yield (from 6.3% to 81.9%) in moso bamboo at 120 °C and ratio of 1:7 (arginine: lactic acid). Results showed degradation of lignin molecules together with release of phenolic hydroxyl units after DESs pretreatment, which is conducive to subsequent utilization. Meanwhile, DES-pretreated cellulose exhibited unique structural characteristics including destroyed crystalline region of cellulose (Crystallinity Index from 67.2% to 53.0%), decreased crystallite size (from 3.41 nm to 3.14 nm) and roughened fiber surface. Thus, arginine-based DES pretreatment has excellent potential in bamboo lignocellulose pretreatment.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
