Abstract

The continuous utilization of ultraviolet (UV) light sources within both academic and industrial contexts necessitates the imperative advancement of alternative UV sources to replace hazardous mercury lamps. Herein, we proposed a mercury-free narrowband UVB (NB-UVB)-emitting device from Y2O3:Gd3+ nanofilm on a tubular quartz substrate. The nanofilm is fabricated utilizing the spin-coating sol-gel precursor technique and is subsequently synthesized via a high-annealing temperature solid-state reaction. This synthesis resulted in the formation of a single-phase cubical structure of Y2O3 characterized by a crack-free morphology. The NB-UVB radiative output with a peak at 315 nm is generated through vacuum UV-induced photoluminescence originating from the emission of Xe excimer, which subsequently excites the Gd3+ luminescent centers incorporated within the Y2O3 host matrix. Moreover, in a high-voltage bipolar power system operating at 19 kV and 19 kHz, the device exhibited an NB-UVB radiance output of 1.34 mW, accompanied by a power efficiency of 0.02 %, whilst preserving exceptional temporal performance. Thus, this investigation introduces an innovative perspective on a mercury-free NB-UVB-emitting device, thereby promoting further exploration into the application of UV radiation sources derived from excimer lamp technology.

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