Abstract

Although substitutions on copper sites always inhibit superconducting properties, the present investigations were successfully promoted mechanical tensile averages for HTc-2223- BPSCCO superconductor with general formula BiPbSr2Ca2Cu3-x(Zn)xO10±δ where x = 0.02, 0.04,0.08 and 0.16 mol respectively in the investigated range without damaging its superconducting features. The study is focusing on the effect of core-shell zinc ions hollow microspheres dopings (x) on the copper sites, where 0 ≤ x ≤ 0.16 mol on the superconducting, mechanical tensile features of 110K-2223-BPSCCO superconductor. The structural and micro-structural features of pure and core shell Zn-doped BPSCCO superconductors samples were carefully investigated by x-ray diffraction (XRD) and scanning electron microscope (SEM). Mechanical tensile measurement indicated that doping ratio (x) with ~0.08 mol is the optimum doping ratio from core shell hollow zinc microspheres achieving maximum tensile average of 51.2 MPa with stroke~0.323 mm acheiving promotion ratio~63.57% in contrast with mechanical tensile measured for pure 2223- BPSCCO superconductor (31.3 MPa with stroke~0.172 mm).

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