Nanoscale Y3AlFe4O12 garnets: Looking into subtle features of crystalline structure and properties formation

Abstract

Nanoscale Al-doped yttrium-iron garnets attract enhanced scientific and practical interest in the development of microwave devices due to their remarkable physical-chemical properties, which depend essentially on the method and conditions of synthesis. This work highlights the advantages of a specific two-stage synthesis of Y3AlFe4O12 garnet ferrite nanoparticles by the precipitation in aqueous solutions and deals with the detailed examinations of the precipitates obtained during this process. The results of the complex studies using high resolution transmission microscopy, dynamic light scattering and magnetic measurements have allowed assessing the features of the formation of crystalline structure. It is demonstrated that the sequence of the precipitation of components during the synthesis strongly affects the physical-chemical properties of the formed precipitate (filtration coefficient value, surface charge, micelle’s structure) as well as the physical properties of nanoparticles obtained after their heat treatment at 800 °C (saturation magnetization, coercive force). Simultaneous precipitation of Fe(OH)3 and Al(OH)3 metal hydroxides, which form one of three crystallographic sub-lattices of the garnet structure, at the first stage of the synthesis of ferrite-garnets is revealed to provide higher values of filtration coefficient of the formed precipitate and better technological and physical-chemical parameters of the fabricated garnet nanoparticles that makes this method highly advantageous for industrial application.