Abstract
Highly-coercive YCo 5-based nanograined powders with composition Y x Co 100− x ( x=16.8–20) have been synthesized by mechanical milling of as-cast alloys and subsequently annealing them. The optimum magnetic properties have been obtained in Y 19.5Co 80.5 powders milled for 4 h and annealed at 950°C for 1 min with a coercivity of 16.0 kOe, a high M r/ M s ratio of 0.67 and a medium-strength maximum energy product ( BH) max of 7.7 MG Oe. Microstructure studies reveal that the Y 19.5Co 80.5 powders have a nearly single YCo 5 structure with a grain size of about 30–40 nm. The high coercivity is attributed to the high anisotropy field of the YCo 5 phase and to its nanoscale grain size.
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