Nanoconfinement of functionalized ionic liquid for enhanced adsorption and rapid sensitive detection of phenylurea herbicides in food and environmental samples

Abstract

The novel ILs@CNTs was synthesized by encapsulating task-specific ionic liquids (ILs) within carbon nanotubes (CNTs) derived from ZIF-67. These hybrid materials served as multifunctional adsorbents enabling simultaneous sorptive removal, sensitive detection, molecular sieve selection, and magnetic separation. In contrast to pristine CNTs, ILs@CNTs demonstrate significantly enhanced adsorption of phenylurea herbicides (PUHs). The complex interactions between ILs@CNTs and PUHs were comprehensively analyzed using a combination of experimental results and theoretical calculations. Furthermore, a magnetic solid phase extraction-high performance liquid chromatography (MSPE-HPLC) method was developed for the determination of multiple trace PUHs in real samples. The method exhibited lower detection limits (0.02–0.03 μg L−1) and higher enrichment factors (131 < EFs < 185). Interestingly, a portable lab-in-a-syringe device was developed to facilitate rapid on-site extraction and enrichment of PUHs. Additionally, the developed methods successfully applied in river water, tea drinks, and cucumber samples, highlighting its substantial potential for rapid PUH detection.