Abstract
HypothesisThe organization of nanoparticles within nanocomposite colloids can imbue added functionality to these suprastructures. We hypothesize that the arrangement of nanoparticles in nanocomposite colloids can be systematically controlled by inducing co-precipitation of oil and a hydrophilic polymer in the presence of nanoparticles with a range of wetting properties. This process will produce oil core/polymer shell nanocapsules with nanoparticles strategically positioned within the suprastructures. ExperimentsCoprecipitation of oil and polymer in the presence of nanoparticles is performed in glass capillary microfluidics. Silica nanoparticles of varying surface properties and morphology are used to investigate the relationship between nanoparticle wetting properties and nanocolloid morphology. The features of the nanocomposites formed are investigated using electron microscopy, sessile drop, and zeta potential measurements. FindingsWhen spherical nanoparticles with wetting properties ranging from hydrophilic to hydrophobic are used, the nanocomposite morphologies formed range from nanoparticles partially engulfed in the polymer shell to nanoparticles embedded in the oil core of the nanocapsule. The number of nanoparticles introduced in the nanocomposite is adjusted by changing their concentration in the precursor solution. The structure of nanocolloids formed with non-spherical or hollow silica nanoparticles depends on their wetting properties.
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