Abstract

We can do so much together: The stereocomplexation of complementary strands of stereoregular poly(methyl methacrylate) (PMMA) to form triple-stranded helices led to a fascinating array of PMMA stereocomplex morphologies. The different polymer-helix assemblies were constructed from a single set of complementary polymers (syndiotactic (blue in the picture) and isotactic PMMA (orange)) by simple tuning of the mixing ratio and concentration.

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