Abstract
The exploitation of ultra-deep oil and gas wells is accompanied by technical problems of ultra-high temperature, especially in the cementing process, which will directly deactivate many admixtures. By in-situ polymerization of the monomers and Nano-SiO2 to improve the temperature resistance, the resulting high temperature resistant composite polymer slurry system can show high efficiency in reducing fluid loss under the high temperature environment of 240℃. The synthesis of the high temperature resistant polymer was characterized by IR and 1H NMR, and its physicochemical properties were analyzed by DLS, GPC, TEM and Cryo-SEM. The synergistic mechanism of Nano-SiO2 on the high temperature resistance of the polymer was revealed by TGA. Using DLS, SEM and EDS, a series of cement slurry systems were used to analyze and compare the effect on fluid loss reduction of different adding methods of Nano-SiO2 in cement slurry at high temperature. The results showed that the grafted Nano-SiO2 polymer maintained effective adsorption capacity at high temperature without degradation, and its fluid loss reduction ability was significantly improved at high temperature. The high temperature resistant composite polymer is strongly adsorbed between cement particles to form a dense and robust spatial network structure. The CSH gel structure is optimized by the particle size gradation of the system, so as to obtain a dense cement cake, which is expected to be applied in high temperature cementing.
Published Version
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