Abstract
In the title compound, C18H22BrN3OS, the piperidine ring adopts a chair conformation. The mean plane of the thiazole ring forms dihedral angles of 23.97 (10) and 75.82 (10)° with the mean planes of its adjacent benzene and piperidine rings, respectively. An intramolecular N—H⋯N hydrogen bond generates an S(7) ring motif in the molecule. In the crystal, no significant intermoelcular hydrogen bonds are observed, but a weak π–π interaction with a centroid–centroid distance of 3.8855 (13) Å occurs.
Highlights
In the title compound, C18H22BrN3OS, the piperidine ring adopts a chair conformation
For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986)
H atoms treated by a mixture of independent and constrained refinement
Summary
El-Subbagh,b Tze Shyang Chiac and Hoong-Kun Func*‡. Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.003 A; R factor = 0.042; wR factor = 0.114; data-to-parameter ratio = 22.7. C18H22BrN3OS, the piperidine ring adopts a chair conformation. The mean plane of the thiazole ring forms dihedral angles of 23.97 (10) and 75.82 (10) with the mean planes of its adjacent benzene and piperidine rings, respectively. An intramolecular N—HÁ Á ÁN hydrogen bond generates an S(7) ring motif in the molecule. No significant intermoelcular hydrogen bonds are observed, but a weak – interaction with a centroid–centroid distance of 3.8855 (13) Aoccurs. See: Cremer & Pople (1975). See: El-Subbagh et al (1999). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986)
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
