Abstract

In the title compound, C19H19N5, the piperidine ring adopts a chair conformation. The pyridine ring is essentially planar, with a maximum deviation of 0.039 (2) Å for a C atom substituted with a carbonitrile group. The mean plane of the central pyridine ring makes the dihedral angles of 37.90 (14) and 56.10 (12)° with the piperidine and benzene rings, respectively. In the crystal, mol­ecules are linked via N—H⋯N and C—H⋯N hydrogen bonds, forming chains along [101], and enclosing R 2 2(17) ring motifs. The chains are linked by further C—H⋯N hydrogen bonds, forming two-dimensional networks lying parallel to (10-1), and enclosing inversion dimers with R 2 2(20) ring motifs.

Highlights

  • In the title compound, C19H19N5, the piperidine ring adopts a chair conformation

  • The pyridine ring is essentially planar, with a maximum deviation of 0.039 (2) Å for a C atom substituted with a carbonitrile group

  • The chains are linked by further C—H N hydrogen bonds, forming two-dimensional networks lying parallel to (101), and enclosing inversion dimers with R22(20) ring motifs

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Summary

Crystal data

Sri Ram Engineering College, Chennai 602 024, India, bDepartment of Chemistry, Pondichery University, Pondichery 605 014, India, and cDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, India.

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