Abstract
In the title compound, C27H29FN2O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluorobenzene ring, which occupies a position coplanar to the methoxy(methylidene)amine residue [N—O—C—C torsion angle = −179.5 (2)°]. In the crystal, a complex network of C—H⋯π interactions connects the molecules into a three-dimensional architecture.
Highlights
In the title compound, C27H29FN2O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions
The dihedral angle formed between the phenyl rings is 66.71 (12), and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13) with the fluorobenzene ring, which occupies a position coplanar to the methoxy(methylidene)amine residue [N—O—C—C torsion angle
Cg1–Cg3 are the centroids of the C1–C6, C16–C21 and C22–C27 rings, respectively
Summary
R factor = 0.041; wR factor = 0.101; data-to-parameter ratio = 9.6. C27H29FN2O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12) , and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13) with the fluorobenzene ring, which occupies a position coplanar to the methoxy(methylidene)amine residue [N—O—C—C torsion angle. A complex network of C—H interactions connects the molecules into a three-dimensional architecture
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