Abstract
In the title compound, C26H27ClN2O, the piperidine ring has a chair conformation and all of the ring substituents at Csp 3 atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogonal to the methoxy(methylidene)amine residue [N—O—C—C torsion angle = −87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supramolecular chains along [010] are sustained by C—H⋯π interactions in the crystal packing.
Highlights
Structure ReportsCentre for Nanotechnology, Department of Chemistry, Kalasalingam University, Krishnankoil 626 126, Tamilnadu, India, bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and cChemistry Department and Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia
In the title compound, C26H27ClN2O, the piperidine ring has a chair conformation and all of the ring substituents at Csp3 atoms occupy equatorial positions
Cg1 and Cg2 are the centroids of the C1–C6 and C15–C20 rings, respectively
Summary
Centre for Nanotechnology, Department of Chemistry, Kalasalingam University, Krishnankoil 626 126, Tamilnadu, India, bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and cChemistry Department and Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia
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