Abstract
In the title compound, C31H27NP2, the diphenylphosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, indicating that it exhibits a distorted trigonal–pyramidal geometry. There are no classical intermolecular interactions.
Highlights
C31H27NP2, the diphenylphosphanyl groups are staggered relative to the PNP backbone
Atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
Summary
C31H27NP2, the diphenylphosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. N atom are 120.84 (16), 113.29 (16) and 120.57 (12) , indicating that it exhibits a distorted trigonal–pyramidal geometry. Data collection: CrystalClear (Rigaku/MSC, 2005); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL
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