Abstract
N-doped carbon nanospheres and porous carbon were produced by a hydrothermal template and the activation of hexamethylenetetramine (HMTA as a nitrogen source and activator) and ZnCl2 (only as an activator) from a poly(Ri-S-ε-CL-PDMS) multiblock/graft copolymer produced using a renewable resource and eco-friendly autoxidation. N-doped carbon nanospheres (PPiSiHMTA) exhibited excellent CO2 adsorption (2.73mmol/g at 0°C and 0.15atm, 1.72mmol/g at 25°C and 0.15atm) and CO2/N2 selectivity (344-512). Despite the higher BET surface area and pore volume, porous carbon (PPiSi) showed low CO2 adsorption (1.21 and 0.71mmol/g, 0.15atm) and CO2/N2 selectivity (57 and 112). PPiSiHMTA and PPiSi have low isosteric heats of adsorption (Qst, 18-33kJ/mol) and stability in humid environments. In addition, PPiSiHMTA exhibited an excellent CO2 recycling performance. The experimental data on CO₂ adsorption was evaluated using various isotherm models, including Freundlich, Langmuir, Sips, and Temkin. The results demonstrated a nearly perfect fit between the Freundlich isotherm and the experimental data, indicating the heterogeneous nature of the adsorbent surfaces. Our study is promising for industrial applications, offering excellent CO2 adsorption, CO2/N2 selectivity, moisture stability, and porous material fabrication strategies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Environmental science and pollution research international
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
