Abstract
After a brief historical survey of organosilicon chemistry, the latest developments in this area are reviewed. Selected topics are : stereochemistry and mechanisms of nucleophilic substitutions at silicon; asymmetric syntheses of organosilicon compounds; organofluorosilanes and -fluorosilicates; utilization of the “disilane fraction” produced by the direct synthesis of methylchlorosilanes; organopolysilanes; silyl metal compounds; silicon-containing small ring systems; divalent silicon species; double-bonded silicon species; and silicon in organic synthesis.
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