Abstract
In the title co-crystal, [Mo(C14H9ClN2O4)O2(CH3OH)]·C10H8N2, the deprotonated Schiff base O,N,O′-chelates to the MoVI atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.006 A; R factor = 0.049; wR factor = 0.138; data-to-parameter ratio = 15.7
In the title co-crystal, [Mo(C14H9ClN2O4)O2(CH3OH)]ÁC10H8N2, the deprotonated Schiff base O,N,O0-chelates to the MoVI atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom
The two hydrogen bonds leading to the formation of a helical chain running along the b axis
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.006 A; R factor = 0.049; wR factor = 0.138; data-to-parameter ratio = 15.7
Sign-in/Register to view highlights & summary 
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call