Abstract
MXenes as an emerging class of 2D materials have great potential in fabricating functional polymer nanocomposites. In this study, Ti3C2T x MXene as a representative MXene filler was employed to prepare sPS nanocomposites. The abundant surface groups (mainly -OH) on MXene allowed facile modification, and thus MXene nanosheets bearing -C12H25 groups were prepared using dodecyl triethoxysiloxane (DCTES) as a modifier. Grafting -C12H25 long alkyl chains onto the surface of MXene strongly affected its affinity towards hydrophobic solvent and the sPS matrix. The rheological threshold concentration (ϕ c,G' = 0.033 vol%) and exponent (β G' = 1.51) and the conductivity threshold concentration (ϕ c,σ = 0.259 vol%) and exponent (β σ = 2.92) were determined by applying percolation scaling laws. The influences of DCTES-modified MXene on the polymorphism, mechanical, thermal and flammability properties of nanocomposites were studied. The obtained nanocomposites displayed not only enhanced mechanical properties, but also improved thermal stability and flame retardancy to some extent. Moreover, the higher the loading level of DCTES-modified MXene, the better was the improved effect.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
