Multistage remediation of heavy metal contaminated river sediments in a mining region based on particle size

Abstract

Sediment pollution is an important environmental problem, and the remediation of heavy metal contaminated sediments is crucial to river ecosystem protection, especially in mining regions. In this work, characteristics of heavy metals (Cu, Zn, Cd, As and Hg) were investigated, including contents and fractions based on particle size (PS) in river sediments. Chemical leaching and stabilization for sediment remediation were performed, and the technology feasibility was assessed. The results indicated that the heavy metals were primarily reserved within fine sediments (PS < 75 μm), comprising 79.8% of the total. For the sequentially extracted fractions, residual fraction dominated the total content in large PS sections (PS > 150 μm), while the oxidizable fraction, reducible fraction and weak acid extractable fraction dominated the total content in fine sediments, except for that of Hg. Chemical leaching can transform most metals in sediments from large-sized particles to fine particles because the metals are absorbed by fine particles in solution rather than complexation. The stabilization suggested that cement could be an effective agent for ecological risk control for heavy metals. In field engineering, a total of 145,000 m3 sediment was divided into various sections by PS and synchronously washed by eluting agents. Finally, clean sediments (PS > 150 μm) were used as building material and clean backfilling; meanwhile, heavily polluted sediments (PS < 150 μm) were buried as general industrial solid waste after stabilization treatment. Over 90% of the contaminated sediments were reused throughout multistep remediation. Furthermore, a reduction in waste and harm, along with resources, was obtained. This study provided a feasible technology for heavy metal contaminated sediment remediation.