Abstract
The development of multisite catalysts that simultaneously satisfy compositional, spatial arrangement and functional requirements remains a significant challenge. Herein, we report a supported Pt catalyst on surface hydroxyl- and oxygen-vacancy-rich H2Ti2O5/TiO2 composite nanotubes for formaldehyde (HCHO) oxidation. Our study demonstrates that H2Ti2O5/TiO2 nanotubes can be prepared by a hydrothermal method and in particular, using Na2[Pt(OH)6] as a metal precursor yields ultrasmall and uniformly distributed Pt nanoparticles on the nanotube surface. In situ diffuse reflectance infrared Fourier transform spectroscopy analyses reveal that HCHO oxidation over the Pt/H2Ti2O5-TiO2 catalyst occurs via a cooperative catalysis mechanism: Pt facilitates the splitting of O2, surface hydroxyl group on H2Ti2O5 serves as HCHO adsorption site and oxygen vacancy on the TiO2 surface promotes the dissociation of H2O to generate active OH species. Consequently, the Pt/H2Ti2O5-TiO2 catalyst exhibits an impressively high mass-specific reaction rate of 118.0 μmol gPt−1 s−1 and excellent stability, outperforming previously reported HCHO oxidation catalysts.
Published Version
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