Abstract
Abstract A multiscale analysis has been conducted on hydrogen-induced intergranular cracking at ambient temperature in medium strength (840 MPa) Ni-Cr steel with antimony, tin, and phosphorous segregation. Combining first-principles calculations and fracture mechanics experiments, a multiscale relationship between threshold stress intensity factor (K th) and cohesive energy of grain boundary (the ideal work of interfacial separation, 2γ int) was revealed. The K th was found to decrease rapidly under a certain threshold of 2γ int, where the 2γ int decreases mainly by mobile hydrogen segregation on fracture surfaces. This segregation is considered to arise during formation of the fracture surfaces under thermodynamic equilibrium in slow crack growth. The resulting strong decohesion probably makes it difficult to emit dislocations at the microcrack tip region, leading to a large reduction in stress intensity factor. Our analysis based on this mobile hydrogen decohesion demonstrates that the K th decreases dramatically within a low and narrow range of hydrogen content in iron lattice in high-strength steels.
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