Abstract
Multiple ligand transfer reaction between planar-chiral cyclopentadienylruthenium complexes [Cp′Ru(AN)3][PF6] [(Cp′ = 1-(CO2Et)-2-Me-4-RC5H2, R = Me, Ph, But, AN = acetonitrile] and iron complexes CpFe(CO)(L)X (L = PMe3, PPh3; X = I, Br) results in formation of metal-centered chiral ruthenium complexes Cp′Ru(CO)(L)X with a diastereoselectivity (de) up to 68%.
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