Multifunctional platinum porphyrin dendrimers as emitters in undoped phosphorescent based light emitting devices

Abstract

The authors report on a class of platinum porphyrin based phosphorescent multifunctional first generation dendrimers (Pt-8Cn-TPP) incorporating a platinum porphyrin core as the emissive center and carbazole side groups as the hole, as well as energy transport fragments. Furthermore, the alkyl groups prevent aggregation and allow for the formation of transparent homogeneous films directly from solution. The intra- and intermolecular energy transfers by Förster and Dexter mechanisms from the carbazole side groups to the platinum porphyrin core have been investigated. Light emitting devices were fabricated and bright red electrophosphorescence was achieved from a single undoped emitting layer of Pt-8C4-TPP. The results indicate that platinum porphyrin dendrimers are very promising to make bright, red saturated and spin-coated phosphorescent devices with a simplified undoped emissive layer.