Multifunctional l-tryptophan derivative induced surface passivation for lateral perovskite photodetectors

Abstract

Organic-inorganic hybrid perovskites have already been employed as promising light-sensitive materials for high-performance photodetectors (PDs) due to their intriguing optoelectronic features. Nonetheless, such perovskite-based PDs often suffer from low sensitivity, high dark current and inevitable degradation. In this work, a novel multifunctional molecule l-tryptophan ethyl ester hydrochloride (l-TEEH) was used to treat the surface defects of triple-cation mixed halide perovskite film. It is found that the modulator with multiple functional groups can effectively passivate the uncoordinated ions (Pb2+ and I-) and halide (I and Cl) vacancies of the perovskite film. Owing to the reduced defects, the dark current of the pristine perovskite PD significantly decreases from ∼ 10-9 A to ∼ 10-11 A after the l-TEEH treatment. Moreover, the perovskite PD with the l-TEEH treatment exhibits a large photoresponsivity (1.27 A/W) and an ultrahigh on/off ratio (∼9 × 103). More impressively, the optimized device shows excellent stability in air with a relative humidity of 40–50 %. Furthermore, the reliable imaging capability of perovskite device with the l-TEEH treatment is also successfully demonstrated.