Multifunctional 1–octadecanol/expanded graphite/Fe3O4 composite phase change materials with effective solar–to–thermal and magnetic–to–thermal conversion and storage

Abstract

Composite phase change materials (CPCMs) with multifunctional thermal conversion and storage abilities have demonstrated exceptional properties for diverse energy storage applications recently; however, these composite materials often encounter limitations of low heat storage capacity and high cost. In this study, novel 1–octadecanol (OD)/expanded graphite (EG)/Fe3O4 CPCMs were facilely prepared and characterized for multifunctional thermal conversion and storage properties. The composites showed excellent thermal energy storage capacities, reaching 185.5 J/g at 80 % OD accompanied by high crystallization fractions of above 95 %. In addition, they exhibited great thermal conductivities, excellent leakage resistance, thermal stability, and reliability. Under simulated solar irradiation, the prepared OD/EG/Fe3O4 CPCMs exhibited a rapid temperature increase from 34 to 70 °C, achieving solar–to–thermal conversion efficiency of 80.2–90.5 %. This behavior can be attributed to its ability to capture and convert photons into thermal energy, facilitated by the synergistic effects of the conjugated double–bond system of EG and localized surface plasmon resonance of Fe3O4 nanoparticles. Furthermore, the prepared OD/EG/Fe3O4 CPCMs exhibited superparamagnetic properties, accelerating their temperatures from 32 °C to 88 °C within 11–23 s when subjected to an alternating magnetic field. This demonstrates magnetic–to–thermal conversion and storage ability. These findings highlight the potential of OD/EG/Fe3O4 CPCMs as promising and cost–effective materials for various practical thermal storage applications.