Multicolor emissive sulfur, nitrogen co-doped carbon dots and their application in ion detection and solid lighting.

Abstract

Multicolor emissive carbon dots (CDs) have potential applications in many fields such as photoelectric display, light-emitting devices, and bioimaging. Such CDs by heteroatom doping of nitrogen elements assisted with various solvents has achieved recently, yet generally low efficiency in red-light region. Herein, we developed a facile route to synthesize multicolor-emissive CDs governed by a solvothermal method of tetrahydrofuran solvent. The maximum emission locates at 432, 510, and 584nm with the absolute FL QYs up to 21.1%, 11.0%, and 55.4% for selected B-CDs, G-CDs, and YG-CDs, respectively. By means of the analysis on their PL spectra, fluorescence lifetimes, and microstructures, the different graphitic degrees and surface states formed under the participation of S and N elements in as-prepared CDs determine the fluorescent color, and large sp2-conjugated domains within the YR-CDs is closely related to high QY. They, likewise, endow the YR-CDs with high sensitivity for ion detections of Ag+ and Fe3+, which was further illustrated to have different quenching mechanisms each other due to the affinity interaction with different surface groups of the CDs. High PL QYs of these CDs emission are beneficial to application in solid lighting, phosphors dried by these CDs solutions were mixed with PVP water solution to fabricate CDs/PVP films. The films exhibited stable fluorescence, and three phosphors were also mixed together in proportion to obtain white-light film with a CIE coordinates of (0.34, 0.34), which demonstrates that these CDs are potentially fluorescent nanomaterial in the solid-state lighting field.