Abstract
This letter reports the first 2D self-assembly of ABC miktoarm star terpolymers based on dual-responsive polycaprolactone-arm-poly(N-isopropylacrylamide)-arm-poly(2-dimethylaminoethyl methacrylate) (μ-CID), which self-assembled into multilayer nanosheets comprising polycaprolactone single crystals in tetrahydrofuran (THF)/methanol mixed solvents. Interestingly, the nanosheets showed pH-responsive morphological transitions in aqueous solutions, yielding multidimensional assemblies, including 2D hexagonal aggregates, patchy nanofibrils, and patchy vesicles, at different pH values. The nanosheets also exhibited thermoresponsive transition to spherical patchy micelles at a temperature above the lower critical solution temperature (LCST) of the poly(N-isopropylacrylamide) block. This study offers a novel system for fundamental study on the self-assembly of miktoarm star terpolymers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
