Abstract
57Fe and119Sn Mossbauer and X-ray diffraction studies have been performed at room temperature to establish the presence of various intermediate phases in the quasibinary sections FeSn2-FeSb2 and FeSn2-FeTe2 {i.e. Fe (Sn1−xSbx)2 and Fe (Sn1−xTex)2 for 0≤x≤1·0 of the respective ternary systems Fe-Sn-Sb and Fe-Sn-Te at 500°C. Using significantly different Mossbauer hyperfine parameters and the X-ray powder diffraction patterns for each existing stable phase, solid solubility limits and presence of single and multiphase regions have been estimated and are reported.
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