Abstract
Applications of Mössbauer spectroscopy to the study of electronic structure properties of non-conducting compounds of neptunium are reviewed. First a brief introduction into the basics of Mössbauer spectroscopy and hyperfine interactions is given. This is followed by a discussion of isomer shift data. Nevt, paramagnetic hyperfine splittings and the influence of spin dynamics on the Mössbauer spectrum are presented together with a few pertinent evamples. A discussion of some recent results on neptunyl compounds follows. Finally some remarks are given concerning heptavalent neptunium and the charge states of neptunium incorporated in glasses.
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