Abstract
Isomer shifts (IS) and quadrupole splittings (QS) are reported for a number of Te compounds. When the isomer shifts for Te compounds are plotted against the isomer shifts for similar I compounds a roughly linear plot results for pairs of compounds which are both isoelectronic and isostructural. Pairs which are not isoelectronic but merely have similar chemical character deviate from the linear relation. For these similar compounds it is noted that the Te-X bonds are more ionic than the I-X bonds. We attempt to make this argument more quantitative and pursue a correlation found to exist between the quadrupole splitting and the isomer shift which is also found to apply to chemically dissimilar Te compounds.
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