Abstract
Measurements on the anhydrous ferrous halides indicate (a) that the Mössbauer quadrupole splitting (QS) and isomer shift (IS) have a common origin and (b) that both properties may provide estimates of 3d electron delocalization. As in the case of similar series of Au, Sn, Sb and Te compounds, the IS in ferrous halides is linearly related to the Pauling electronegativity.
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