Morphological, thermal and mechanical properties of wheat‐straw reinforced copper nanocomposite

Abstract

AbstractThe work summarizes an innovative nanocomposite including synthesized copper nanoparticle (CuNP) impregnated wheat straw (WS) (the agronomic waste from an wheat plant) reinforced unsaturated polyester resin has been established. The addition of nanoparticles (NPs) increased the antifungal properties (~11%), durability (~9%), and strength (~39%) of the composites. Therefore, these nanoparticles have been synthesized from a copper chloride dihydrate precursor and they have been impregnated into wheat straw via cationization. This copper‐impregnated wheat straw (CuIWS) was formulated and employed to create a strong and long‐lasting nanocomposite with unsaturated polyester resin. Their morphological, mechanical, chemical, biodegradability (BD), and thermal properties were estimated and relationships were explicated systematically. Particularly, the tensile strength of polyester resin, crude and treated WS (cationized and copper‐impregnated) composites were 11.70, 14.20, 20.92, and 22.34 N/mm2 respectively. Therefore the reinforcement capability for crude, cationized and copper‐impregnated WS composites increased by ~22%, 75%, and 92% respectively. The residual ash was just about 16.23%, 12.04% and 6.56% for copper impregnated wheat straw composite (CuIWSC), Cationized wheat straw composite (CWSC) and untreated wheat straw composite (UTWSC) respectively point to the existence of ~4.1% Cu incorporated into the wheat straw which holds up the energy dispersive x‐ray (EDX) spectra of ~4.2% copper content. Thermogravimetric analysis (TGA) indicates that the nanocomposites are stable up to 325°C. These nanocomposites also show superlative crystallinity compared to other ones. Water uptake capacity followed typical Fickian diffusion law. The developed nanocomposites might be suitable for automobile and aircraft parts, furniture, and other indoor to outdoor applications.Highlights TS of the composites increased by increasing the WS filling up to 15%. The crystallinity increased after the addition of nanoparticles. The typical water uptake properties followed the Fickian diffusion rule. Incorporation of nanoparticles increased 11% antifungal properties. The developed nanocomposites are used for inside and outside applications.