Abstract

AbstractThe influence of energetic parameters of the interchain homo‐ and heterocontacts on a local ordering of Bernoullian copolymers has been studied using Monte Carlo simulations and probabilistic analysis. The results of both methods are in a good agreement. Then simple Monte Carlo procedure was employed to study the ordering in products of a polymeranalogous reaction with accelerating effect of neighboring groups. When the reaction with intra‐ and interchain acceleration and local ordering proceed simultaneously in confined conditions, the ordering might affect the process so that the formation of certain nano‐structures (in particular, not trivial strip‐like ones) is possible.

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