Abstract
For the first time, the rate constant of the thermal monomolecular decomposition of n-C3F7I in Ar was measured directly using the technique of atomic resonance absorption spectroscopy on a resonant line of iodine atom. Experiments were conducted behind the incident and reflected shock waves in a broad range of thermodynamic parameters (T = 800–1200 K and P = 0.6–8.3 bar). Experimental data were found to conform reasonably to the results of the Rice–Ramsperger–Kassel–Marcus theory master equation modeling based on the results of quantum chemical calculations. The obtained low- and high-pressure limiting rate constants for n-C3F7I and CF3I dissociation in Ar were reported. Third body efficiencies for Kr were also evaluated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
