Monolayer 2D quantum materials subjected to gamma irradiation in high-vacuum for nuclear and space applications

Abstract

The stability and reliability of emerging two-dimensional (2D) quantum materials subjected to harsh environments, such as high-energy radiation, are of high importance, particularly in the fields of space, defense, and energy applications. In this work, we explored the effects of gamma radiation on the structural and optical properties of monolayer WSe2 and WS2 crystals. Raman and photoluminescence spectroscopies were employed to study and probe radiation-induced changes to the samples after exposure to intense gamma radiation (from a 60Co source) in a high-vacuum environment (∼1 × 10−6 Torr) and with various exposure times to vary the total accumulated dosage (up to ∼56 Mrad). In general, very small changes in optical or vibrational properties were observed compared to pristine samples, suggesting noteworthy stability even for high dosages of gamma radiation. Moreover, we found that WSe2 monolayer samples exhibited higher tolerance to gamma radiation compared to WS2 samples. These findings highlight the inherent stability of these 2D quantum materials in harsh radioactive environments, which motivates further investigation of their optical, electrical, and structural properties and exploration for use in future space, energy, and defense applications.