Abstract

GaAs epilayers have been succesfully grown by chemical beam epitaxy (CBE) using unprecracked monoethylarsine, which appears to be a viable replacement for arsine in CBE applications. Undoped GaAs epilayers were grown using unprecracked monoethylarsine (MEAs), trimethylgallium (TEG) at growth temperatures of 540 to 660°C, and V/III ratios from 5 to 30. All films grown using TMG under these conditions were p-type. n-Type background doping was also observed in TEG-grown epilayers with low carbon concentration. Secondary ion mass spectrometry and photoluminescence measurements of films grown by MEAs show that the carbon concentration is less than that in epilayers grown by precracked arsine. Intermediates like dihydrides from MEAs decomposed on the surface are considered to supply hydrogen atoms and hydrides during growth, which may remove other carbon containing species.

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