Abstract
Tetraethylammonium tris[diethylthio-, di(n-butylthio)- or trimethylenedithio-tetrathiafulvalenyl(TTF)dithiolato] vanadium complexes (NEt 4 +1a,b,c - ) were oxidized with iodine to give the corresponding neutral complexes (1a,b,c), in which one unpaired electron is preferentially distributed at the TTFdithiolato groups. The compressed pellets of 1a,b,c exhibited comparatively low room-temperature electrical conductivities (σ RT 's) of 10 -(4-8) S cm -1 , which are however higher by 10 2-6 times than that (<10 -10 S cm -1 ) in a neutral bis(5,6-dihydro-1,4-dithiin-2,3-dithiolato) vanadium complex, V(DDDT) 3 .
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.