Monitoring of fumarole discharge during the 1975–1982 rifting in Krafla volcanic center, north Iceland

Abstract

Abstract Fumarole discharge chemistry in the Krafla geothermal field changed regionally during the 1975–1982 rifting activity. The discharge chemistry previously encountered in the Krafla fumarole grounds was masked by a carbon dioxide-rich gas during the first weeks of rifting. The new discharge composition remained unchanged until 1983 when the first signs of recovery of the previous equilibrium composition appeared at the margins of the area. The outgassing carbon dioxide is released from the deep aquifers beneath the area by the interaction of magmatic gas with the hydrothermal system. In addition to juvenile magmatic carbon the outgassing contains carbon released from the hydrothermal systed upon reaction with acid magmatic gases. Increased boiling of the hydrothermal fumaroles was induced by the lowering of the partial pressure of steam due to increased gas content in the fumarole conduits. At the center of rifting activity above the magma chamber the fumarole discharge was temporarily mixed with magmatic gases during local effusive activity. Hydrogen was the dominating magmatic gas in that discharge due to the preferred degassing of hydrogen from magma at shallow levels. These “hydrogen pulses” increased in magnitude and duration towards the end of rifting in 1982. The discharge chemistry correlates with the expansion of the magma reservoir of the volcano (regional change of long duration) and local volcanism (short-lived change, hydrogen pulses). The chemical monitoring of fumaroles in Krafla shows that the chemical surveillance of volcanos needs rapid methods for sampling and complete chemical analysis which can be interpreted in terms of reactions and magmatic processes.