Abstract
Abstract For the first time it has been possible to prepare complexes of Mo(V) with the following aliphatic diamines: 1,2 ethylenediamine (en), 1,3 trimethylenediamine (tn), 1,4 tetramethylenediamine (bn), 1,5 pen-tamethylenediamine (pn), 1,6 hexamethylenediamine (hn) and 1,8 octame-thylenediamine (on). Analytical results show that all the complexes prepared correspond to the empirical formula [Mo2Cl2(AA)8] Cl8 where AA is the diamine. The measurement of paramagnetic susceptibilities underlines the diamag-netic nature of all the compounds. Thermogravimetric studies reveal very similar behaviour in all cases with the final formation of MoO3. According to i.r. spectra, diamines act as monodentate ligands, and the Moatoms are bridged through chlorine ligands. Electronic spectra show no bands in the visible region.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
