Abstract
Abstract The Mo(V) complexes with the following aliphatic compounds, 1,9 nonanediamine (nn) and 1,10 decanediamine (dn), have been prepared according to a modified procedure described in a previous paper. Analytical results revealed the two complexes obtained had a stoichiometry of [Mo2Cl2(AA)4] Cl8, with AA as the diamine. The paramagnetic susceptibility measurements suggest the diamagnetic nature of the two compounds. Both complexes behaved similarly in thermogravimetric studies, and in both cases the processes resulted in the formation of MoO3. The i.r. spectra showed that the diamines act as bidentate ligands and it is suggested that the molybdenum atoms are bridged through chlorine ligands. No bands were seen in the visible zone of the electronic spectra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
