Molten salt induced strong interaction between Co3O4 and montmorillonite for the promoted peroxymonosulfate activation toward tetracycline degradation

Abstract

Cobalt-based materials exhibit great premises for activating peroxymonosulfate (PMS) toward water remediation. Generally, active Co species are anchored on the surface of supports to improve the utilization efficiency, yet the stability of the catalyst is difficult to resolve due to the weak interaction between the active species and the support. Herein, a molten salt method is employed to reinforce the interfacial interaction between Co3O4 and montmorillonite (Mt) support. The use of molten Na3PO4 can mitigate the dehydroxylation process of Mt, and thus the electronic structure of Co3O4 NPs can be regulated by the surface hydroxyl species more efficiently. Consequently, the prepared Co3O4/Mt displays an enhanced CoII/CoIII ratio, and the degradation of tetracycline (TC) could reach 99% in 7 min by the PMS-based advanced oxidation process. Meanwhile, the TC removal efficiency can still reach 96% after 8 cycles, and the Co ion leaching is over 10 times lower as compared with the catalyst prepared not using the molten salt. This study highlights the significance of the molten salt method for enhancing the strong interfacial interaction, which is crucial to regulating the nature of supported catalysts, and provide satisfactory Co-based catalyst for PMS activation toward TC degradation.