Molekularstrahl-Experimente an zweiatomigen Molekülen in angeregten Schwingungszuständen: Elektrisches Dipolmoment und Quadrupolkopplungskonstante von CsF bisv=8

Abstract

Radio frequency spectra of CsF in the rotational stateJ=1 have been measured for the vibrational statesv=0, 1,..., 8 using the molecular beam electric resonance method. The analysis of the spectra yields the electric dipole moment μv and the quadrupole coupling constanteqvQ connected with the quadrupole moment of the Cs nucleus. The results are: $$\begin{gathered} \mu _\upsilon = 7.8478 + 0.07026(\upsilon + 1/2) + 0.000195(\upsilon + 1/2)^2 debye \hfill \\ eq_\upsilon Q/h = 1245.2 - 16.2(\upsilon + 1/2) + 0.31(\upsilon + 1/2)^2 kHz. \hfill \\ \end{gathered} $$