Abstract
The molecular beam electric resonance method was employed to obtain a complete set of hyperfine Λ doubling transitions of the free radicals OH, OD, SH, and SD. The observed spectra could be explained very well by the degenerate perturbation theory adapted to the 2Π state. The experimental results include fine and hyperfine coupling constants, the electric dipole moments could be explained very well by the degenerate perturbation theory adapted to the 2Π state. The constants agree well with ab initio calculations.
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