Molecular thermodynamics on the basis of an equation of state for argon. II. Binary mixtures of weakly nonspherical molecules

Abstract

Using a molecular perturbation theory based on an equation of state for pure argon, excess properties and vapor-liquid equilibria are predicted for various binary mixtures composed of weakly nonspherical molecules. The results are rather satisfactory and generally much better than obtained using typical empirical methods. It is further demonstrated that a binary parameter in the dispersion energy results in only modest improvement