Abstract
Crystals of the title compound are monoclinic, space group P21/n with a= 11.291 ± 0.010, b= 21.01 8 ± 0.015, c= 14.380 ± 0.010 A, β= 95.54 ± 0.05°. The structure was determined from counter intensity data by heavy-atom techniques and refined by block-diagonal least-squares to R 0.053 for 5 110 reflections. Important mean bond lengths are : Pt–As 2.435, Pt–C 2.01 5, and C–C 1.45 A. The extent of rehybridisation of the olefinic carbon atoms is discussed and the geometry of the complex compared with that in related molecules.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Dalton Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
