Abstract
Molecular dynamics (MD) study of equilibrium system of a single argon nanodroplet and its surrounding argon vapor is carried out to address a fundamental issue whether the thermodynamic description is applicable to the nanoscale inhomogeneous system. The numerical result is sufficiently reliable so that it can identify the smallest droplet standing stably over 200 ns. The validity of the Laplace equation for nanodroplet is proved by a purely mechanical argument on the basis of directly computed normal and tangential pressures in the transition layer. Furthermore, it is demonstrated that the chemical potentials of liquid and vapor phases are not equal when a droplet is so small that the number of molecules consisting the transition layer may be comparable to that in the droplet. The Kelvin equation does not hold in such a case.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
