Abstract
By means of molecular dynamics simulation the effect of external electric field on charged chains in the liquid state is investigated. Three types of hypothetical chains with different charge and weight distributions are studied. External electric fields with different forms, field strength and frequency are examined. Results indicate that the populations of trans and gauche configuration, the dipole moment of the chain, the dihedral angle correlation function and the sequence of trans and gauche configuration are sensitive to the strength and form of applied external field. The result and significance of each of these properties are discussed.
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