Abstract
A normal co-ordinate analysis of the tungsten chloride pentafluoride molecule has been carried out following Wilson's FG matrix method using a general quadratic potential function, and a set of potential energy constants is reported. The analysis supports the assignments given by Adams et al. Thermodynamic properties—heat content, free energy, entropy and heat capacity—for ideal gas state at one atmosphere pressure and with usual rigid rotor harmonic oscillator approximation have been calculated for twelve temperatures from 100 to 1000°K.
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