Abstract
A normal coordinate analysis of methyl cyanide (CH 3CN) and methyl isocyanide (CH 3NC) has been made, following Wilson's FG matrix method. The potential energy constants thus obtained were then used in the evaluation of the rotational distortion constants. Molar thermodynamic properties—heat, content, free energy, entropy, and heat capacity—for the ideal gaseous state at one atmosphere pressure, and with the usual rigid-rotor harmonic-oscillator approximation, also have been calculated for 12 temperatures from 100 to 1000°K.
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